船舶装运硫磺须知

船舶装运硫磺须知

Instruction for shipping sulphur

硫磺，分子式：S，粉状比重1.956，块状比重2.046，熔点为120℃，沸点为444.6℃，燃点为255℃，属于危险品；联合国编号(UNNO)1350，国际危规页码(IMDG CODF—PAGF)4174，危险类别为4.1类易燃固体；

Sulfur, molecular formula: S, the specific gravity powder is 1.956, bulk specific gravity is 2.046, melting point is 120 ℃, boiling point is 444.6 ℃, ignition point is 255 ℃. It belongs to hazardous materials; UN number (UNNo) is 1350. IMDG page number (IMDG CODF- PAGF) is 4174. Its hazard class is 4.1, and belongs to flammable solids;

特性：不溶于水，易燃；与大多数氧化物质，会形成爆炸性和极端敏感的混合物；遇火时，释放出毒性的、强刺激和窒息性的气体；对钢板等金属物有腐蚀性（尤其是在潮湿情况下）；休止角35-40℃。

Properties: insoluble in water, flammable; with most oxide materials, will form a mixture of explosive and extremely sensitive; case of fire, release toxic and strong stimulation, and asphyxiating gas; of corrosive steel and other metal objects (especially in wet conditions); angle of repose 35-40 ℃.

硫磺的运输，关系到船舶人员安全和货运质量，应予以高度重视，不得疏忽、麻痹。装运时，应严格执行以下规定。

Sulfur transportation is related to the safety of the ship and cargo mass, and should be attached great importance. No negligence. In the process of shipment, the following provisions should be strictly enforced.

1. 接到航次任务后，应召开相关人员会议，认真学习《国际危规》中有关规定及中远集团总公司《远洋船舶货运质量规章制度汇编》中《关于硫磺安全运输的进一步探讨》等相关文章，制定切实可行的安全措施，并严格执行；

After receiving the task of transportation, relevant staff meetings should be held to seriously study \"the IMDG Code\" in the relevant regulations and COSCO \"compilation of ocean-going vessels cargo quality rules and regulations\" in the \"Further on the safe transport of sulfur\" and other related articles to develop practical security measures and strict implementation;

2. 装运前的准备Preparation before shipment

2.1. 认真、彻底清扫货舱，做到清洁、干燥、无浮锈、无油漆皮、无剩余异物，使之达到完全适货（装粮清洁）的程度；确保一次性通过验舱。

The careful and thorough cleaning cargo hold, so that clean, dry, no rust, no paint, leather, no remaining foreign bodies, so as to reach full fitness goods (with grain cleaning) levels; to ensure success in the test chamber.

2.2. 由于该货种对船体钢板具有腐蚀性，装载前应在货舱内喷涂石灰水(LIMFWASHING)，并应注意下列事项：

As the steel hull cargo corrosive species, loading in the cargo hold before spraying lime (LIMFWASHING), and should note the following:

2.2.1. 船舶接到装运硫磺任务后，应立即联系租家或相关部门提供熟石灰、奶粉等必要材料；如不能及时提供或不予提供奶粉，请立即与公司调度或有关部门联系，协助解决。

The ship received a shipment of sulfur mission, should immediately contact the relevant departments to provide rental home or slaked lime, milk powder and other necessary materials; if they can not provide timely or not to provide milk, please contact the company or the relevant department scheduling, to solve.

2.2.2. 应了解供船石灰的特性。必要时，应进行试验。（据了解，日本供船的熟石灰粉附着力比较强，不易清除。）

Should be aware of the characteristics of lime for the ship. Necessary, should be tested. (It is understood that the Japanese ship's white lime powder for the relatively strong adhesion, easy to remove.)

2.2.3. 常用石灰水配比：熟石灰75KG、奶粉2KG、淡水200KG，搅匀后使用。

The ratio of common lime: hydrated lime 75KG, milk 2KG, water 200KG, and stir well before use.

2.2.4. 石灰水应达到一定浓度。尤其是舱底板和靠近舱底板的舱壁处，浓度要尽量大一些，尽量降低硫磺对舱内钢板的腐蚀；

Lime water should reach a certain concentration. Especially near the bilge board bilge board and the bulkhead, the concentration should be as large as some, try to reduce the sulfur on the corrosion of steel tanks;

2.2.5. 喷涂高度要适中。过低，会使无保护部位钢板受到硫磺的腐蚀；过高，将会给卸货后的清舱工作困难。计算货物堆装高度时，应将货物呈“山”字形堆装考虑到；石灰水喷涂的高度应稍高于货物堆装高度（但严禁喷涂过高）；

Spray height should be moderate. Too low will lead to unprotected parts of steel corrosion by sulfur; too high, will hold cleaning to work after discharge difficult. Calculation of cargo stowed height, should the goods were \"mountain\" shape stowed into account; lime spray height should be slightly higher than the cargo stowed height (but non-spraying too high);

2.3. 石灰水喷涂程序及注意事项：

Lime spraying procedures and precautions:

2.3.1. 喷涂前，准备工作要充分。应召开全船会议，做好动员工作，并备妥相关工具，做好人员分工。

spraying, to fully prepare. Meeting should be held the ship and do mobilization and to make available tools, good personnel division.

2.3.2. 工具准备：备妥两个潜水泵（扬程在25-30M）和相应的水管；制作潜水泵控

制阀（可控制水泵的流量大小）；备妥六个干净的油桶。

Tools ready: ready for two submersible pumps (lift the 25-30M) and the corresponding water; making submersible pump control valve (pump flow rate can be controlled size); available six clean oil drums.

2.3.3. 可用两个大桶调和熟石灰粉。配方：熟石灰粉75KG，奶粉1KG，淡水200KG，搅匀后使用（每个大舱约需300KG熟石灰粉）。再用一个空桶放一个台潜水泵，出水管和回水管可用皮龙管接，连接出口管可用细胶管，然后将调好的石灰水倒入桶内开动潜水泵，连接出口管可用细胶管，然后将调好的石灰水倒入桶内开动潜水泵，调好流量，即可喷刷；

Lime powder can be used to reconcile the two vats. Recipe: hydrated lime powder, 75KG, milk powder 1KG, freshwater 200KG, stir well before use (about 300KG each large compartment white lime powder.) An empty bucket and then put a submersible pump, water outlet pipe and return pipe can be connected hoses, hose connection outlet pipe can be fine, and then tuned into the barrel lime start pump, outlet pipe connection available thin hose, and then tuned into the barrel lime submersible pump start and adjust flow rate, can be sprayed;

2.3.4. 喷刷方法：应先从船首喷向船尾方向，从上往下喷，使石灰水从高处流向低处；舱底、舱壁斜坡处可用扫帚将石灰水扫匀。

spray methods: should start playing in the stern direction of the bow, spraying from the top down, so that the flow of lime from the high and low; bilge, bulkheads slope at the lime used brooms sweep evenly.

2.3.5. 喷刷标准；喷刷在舱底、舱壁裸露处的钢板，石灰水的浓渡 要大一些，厚一些，可尽量降低硫磺对舱内钢板的腐蚀；干后，应看不到舱底、舱壁的原色，呈纯白色即可。

sprayed standards; sprayed in the bilge, bulkheads exposed at the plate, the concentration of limewater transition to larger, thicker, sulfur can minimize the corrosion of steel tanks; when is dry, primary color should not be found in bilge or on bulkheads, was pure white can be.

2.3.6. 喷涂石灰水前后和装货前后均应拍照，作为装运资料。一旦货舱出现锈蚀问题，便于船东向货方、承租人提出索赔；如果是租船，且是第1次喷涂石灰水，船长一定要向承租人写出船长声明。

Spraying lime should be photographed before and after loading, as the shipping information. Once the cargo space corrosion problem and to allow the cargo owner, the tenant claims; If the charter, and is the 1st spray lime, the captain must write to the master lessee a statement.

2.4. 检查、试验通过货舱内的压舱水管路及其它管路、电线等，保证不漏水、不漏油、不漏电，保证污水沟、井畅通清洁；油污要擦净，应随时排放；用麻袋封好污水井盖板，防止航行中船舶摇摆致使硫磺渗入，堵塞污水井；

The inspection, testing through the cargo holds, ballast water pipeline and other pipelines, cables, etc. to ensure the watertight, no leakage, no leakage, ensure Wu Hugo, well smooth clean; oil to wipe and be ready to discharge; with sewage covers board sacks sealed to prevent the sailing of the ship causing sulfur

into swing, clogging water wells;

2.5. 检查各货舱舱盖水密情况。发现问题应立即解决；不能解决的，待全部装货完毕，将所有舱盖间隙用布条和油漆封死，保证水密；

Check the cargo hatch watertight case. That issue should be resolved immediately; can not be solved until all of the loading is completed, all hatch gap sealed with cloth and paint to ensure the watertight;

2.6. 检查各种活动灭火机及消防水管、消防皮龙，使之处于正常良好状态；

Check the various activities extinguishers and fire water pipes, fire hoses, so that in normal good condition;

2.7. 验舱应一次通过，使货主、租家、验舱人员和有关方面满意，并取得验舱证书；

Time through the test chamber to be, so that the owner, rental home, holds staff and stakeholders satisfied with the inspection and obtain certificate of inspection chamber;

2.8. 抵港后，申请主管当局监装并取得监装证书。

when arrival, apply administrative authority to monitor and obtain a Certificate of supervision.

3. 硫磺的装运

Shipment of sulfur

3.1. 动员全船人员，思想高度重视。值班驾驶员和值班水手要认真监装、监卸、严格把关。

Mobilize the whole ship of people, ideas seriously. Duty pilots and sailors on duty should seriously supervision of loading and unloading, strict control.

3.2. 装载硫磺时，有粉尘飞扬。部分港口（因货物污染海面）限制白天装货。为保证船期，可采用一边装，一边用喷水器喷洒淡水的方法，减少空气污染和硫磺粉尘飞扬；

Dust flies when loading sulfur. Part of the port (due to pollution of the sea cargo) loading restrictions during the day. To ensure the timetable, can be installed side while spraying water with the sprinkler method, to reduce air pollution and dust emissions of sulfur;

3.3. 甲板值班人员一定要戴防风眼镜，穿戴整齐，以防硫磺粉对眼睛和皮肤的侵蚀；

deck duty must wear windproof glasses, dressed to prevent sulfur powder on the eyes and skin erosion;

3.4. 靠近机舱的货物应斜坡式装载，使其与后舱壁隔开；

near the engine room of the goods shall be sloping loading, and after it separated from the bulkhead;

3.5. 装货后，应立即将舱盖轨道上撒落的硫磺用清水冲洗干净；

loading, should be immediately scattered the sulfur hatch track rinse with water;

3.6. 硫磺在船期间，一定要落实防火措施。甲板及舱内严禁吸烟及明火作业；货舱灯要加网罩，且应放置位置妥当，及时收放；

During the sulfur in the boat, be sure to implement fire safety measures. Non-smoking deck and holds and fire operations; cargo lights to add nets and should be placed properly and timely retractable;

3.7. 密切注视天气变化，雨雪天气及时关舱，防止货物受潮；

closely monitor changes in the weather, rain and snow off spaces in time to prevent the cargo damp;

3.8. 航行中不必进行通风。通风口应用帆布盖好，防止火星进入舱内。

It is not necessary to ventilate ship’s holds on the way. Vents are covered with tarpaulin to prevent mars enter the holds.

3.9. 货舱双层底燃油舱尽量不加温。如需加温，应先取得船长同意，并且必须安排专人负责监视加温情况。加温应控制至驳动油为止，油温应控制在50℃以下，或视危险货物的特性及积载情况相应地控制油温。油舱油少更加注意加温，严禁空油舱加温。(据介绍180燃油海温28—30℃可以不加温)；

double bottom fuel tanks hold as much as possible without heating. For heating, the master agreement should be obtained and must arrange for staff to monitor heating situation. Heating should be controlled to move the oil barge until the oil temperature should be controlled below 50 ℃, or, as the characteristics of dangerous goods and the stowage of the circumstances, to control the oil temperature. Pay more attention to the oil tank be heat, prohibit heating to empty oil tanks. (It is reported that sea surface temperature 28-30 ℃ 180 fuel can not heated);

3.10. 如遇大风浪航行(风力9级、浪8级)，请备妥海事声明；船舶抵达第一卸港时，即应办理签证；

In case of stormy sailing (wind 9, waves 8), make available the Marine

statement; arrival of the ship when the first discharge port, which should apply for a visa;

3.11. 卸货前，如天气允许，可提前打开舱盖；

before discharge, such as weather permits, open the hatches in advance;

3.12. 开启舱盖不宜过快，防止撞击产生火花。

Open the hatch should not be too fast to prevent the crash sparks.

3.13. 施放舱内硫磺挥发的气体，用淡水喷洒在货物表面上；

release volatile sulfur gas tank with fresh water sprayed on the surface of the goods;

3.14. 卸硫磺时，必须切实加强防火工作，增派值班人员，加强24小时巡视；

discharge sulfur must strengthen fire prevention work, additional duty, to enhance 24-hour patrol;

3.15. 严禁吸烟，防止火种进入作业现场，防止起火或爆炸事故的发生；

no-smoking, to prevent the fire entering the job site, to prevent the occurrence of fire or explosion;

3.16. 卸货中发现硫磺燃烧，需立即用淡水喷灭；灭火时要防止燃烧气体对人员造成危害；

3.17. （注：淡水对硫磺品质几乎没有影响，消防用水应用淡水；海水对硫磺品质有较大影响，如用海水灭火，易造成货损。）

discharge of sulfur found in burning off to be sprayed immediately with fresh water; fire fighting personnel to prevent harm to the combustion gases;

(Note: the quality of fresh water had little effect on the sulfur, fire water, application of fresh water; water quality have a greater impact on the sulfur, such as fighting with the sea, could easily lead to cargo damage.)

3.18. 货物将要卸毕时，由于抓头触碰舱底，铲车摩擦舱底板，容易引起硫磺起火；要尽早发现、尽早扑灭（一般卸货方在船边有消防人员值班）。

Goods will be completed unloading, the gripper touch bilge, bilge forklift friction plate, easily lead to sulfur fire; to early detection, early fight (usually discharge a fire side of the boat side on duty).

3.19. 货物卸毕，应尽快清洗货舱。清洗货舱应尽量避免扬起粉尘，造成对人员的危害和引发爆炸事故；洗舱时应先用淡水冲洗，再进行清扫；船员扫舱时不得吸烟。

（注：硫磺粉尘易引起呼吸道疾病，且当浓度达到一定程度时会引发爆炸事故。）

Completion of discharge of goods, cargo should be cleaned as soon as possible. Cleaning should avoid stirring up dust cargo hold, causing harm to personnel and cause explosion; washing should be washed with fresh water, and then the cleaning; crew stripping is not allowed to smoke.

(Note: Sulfur dust can lead to respiratory disease, and when the concentration reaches a certain level will cause explosion.)

3.20. 硫磺由于受到碾压和油舱加温等影响，熔化后粘结在舱底板和舱壁上，硬度较大，致使清舱难度很大。可用6KG高压水加6KG高压空气冲洗。

Due to rolling and sulfur heating oil tanks and other effects of melting plate and bulkheads bonded in the bilge, the hardness of a larger, resulting in clear

space is very difficult. Add 6KG available 6KG high-pressure air high-pressure water rinse.

3.21. 由于硫磺腐蚀性强，洗舱后应对污水系统的管路进行较长时间的冲洗，以防残留硫磺对管路的腐蚀。

As sulfur corrodes, after washing the holds, wash the sewage system for a long time, to prevent corrosion of residual sulfur on the pipe.